Preheat the oven to 325 degrees convection bake (if you're using convention bake ovens, you'll need to bake your cakes a little longer is all). Prep three 6" cake rounds with a swipe of shortening and dust of flour to prevent sticking. Set aside.
In a medium bowl, stir together the buttermilk and 1/2 cup of the cocoa pebbles cereal for about 20 minutes (this is great to do while waiting for the buttermilk to come to room temperature before baking anyway).
In a large bowl, hand-whisk together the buttermilk-cereal-soak-mixture, sour cream, eggs, oil, and vanilla until thoroughly combined. Toss in the other 1/2 cup of the cocoa pebbles cereal, and then sift in the devils food cake mix. Gently stir until just combined.
Split the cake batter between prepared cake rounds and bake for 25-27 minutes. After cooling in the pan for less than a minute, flip out the cake rounds onto a wire rack to cool completely. Wrap up with plastic wrap and freeze until you're ready to assemble. It's much easier to assemble with chilled or partially frozen cake layers.